Published June 1981 | Version v1
Journal article

On the structure of Ba3SmRu2O9, Ba3SmIrRuO9, and Ba2InIrO6

  • 1. Tuebingen Univ. (Germany, F.R.). Lehrstuhl fuer Anorganische Chemie 2

Description

The compounds Ba3SmRu2O9, Ba3SmIrRuO9, and Ba2InIrO6 have a hexagonal BaTiO3 structure (sequence (hcc)2) with an ordered cationic distribution. The 6 L stacking polytypes Ba3BM2O9 show an 1:2 order (M2O9 double octahedra and BO6 single groups) and crystallize in the space group P63/mmc. The refined, intensity related R' values are 6.9% (Ba3SmRu2O9) and 6.5% (Ba3SmIrRuO9). The 1:1 ordered Ba2InIrO6, with InIrO9 double groups and InO6-, IrO6-single octahedra, belongs to the space group P-3m1; the refined R' is 7.3%. (author)

Additional details

Additional titles

Original title (German)
Zur Struktur von Ba

Publishing Information

Journal Title
Z. Anorg. Allg. Chem.
Journal Volume
477
Series
Z. Anorg. Allg. Chem.
Journal Page Range
161-166
ISSN
0044-2313