Published September 2017 | Version v1
Journal article Metadata-only

Novel olefin metathetis catalysts with fluorinated N-alkyl-N´-arylimidazolin-2-ylidene ligands

Creators

  • 1. A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (Russian Federation)
  • 2. CNRS -Universitŭ de Rennes 1, Institute des Sciences Chimique de Rennes, Organomŭtalliques: Matŭriaux et Catalyse, Centre for Catalysis and Green Chemistry, Campus de Beaulieau (France)

Description

Novel ruthenium carbene complexes bearing unsymmetrical NHC-ligands based on N-alkyl-N´-arylimidazoline with hexafluoroisopropylmethoxy group in para-position of N-aryl moiety have been synthesized. Catalytic activity of complexes obtained was investigated on model reactions of intra- and intermolecular olefin metathesis.

Additional details

Identifiers

DOI
10.1007/s11172-017-1930-5;

Publishing Information

Journal Title
Russian Chemical Bulletin
Journal Volume
66
Journal Issue
9
Journal Page Range
p. 1601-1606
ISSN
1066-5285
CODEN
RCBUEY

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
51025386
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKENES; CARBENES; CATALYSIS; CATALYSTS; COMPLEXES; LIGANDS; RUTHENIUM
Descriptors DEC
ELEMENTS; HYDROCARBONS; METALS; ORGANIC COMPOUNDS; PLATINUM METALS; RADICALS; REFRACTORY METALS; TRANSITION ELEMENTS

Optional Information

Copyright
Copyright (c) 2017 Springer Science+Business Media, LLC, part of Springer Nature
Notes
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