Aqueous micellar solutions of Imidazolium based surface active ionic liquids: Promising solvent systems to boost the electrocatalytic performance of Vitamin B12 toward eco-green electro-detoxification of halocarbons

Vitamin B₁₂ (VB₁₂) is considered as a promising molecular catalyst for a diverse range of important industrial, synthetic and environmental electrochemical transformations. However, the low turnover frequency (TOF) and the solubility concerns pose serious challenges in harnessing the electrocatalytic potential of VB₁₂ for these applications. Herein, we demonstrate that aqueous micellar solutions of SAILs viz. 1-dodecyl-3-methylimidazolium chloride ([DDMIM][Cl]) and 1-butyl-3-methylimidazolium dodecyl sulfate ([BMIM][DS]) enhance by several orders the electrocatalytic efficiency of VB₁₂ toward electroreduction of bromoacetonitrile. Our extensive voltammetric investigations, as recommended for the benchmarking of molecular catalysts, viz. Foot of Wave Analysis, catalytic Tafel plots and the resulting estimates of electrocatalytic parameters like TOF and TOF at zero overpotential, clearly establish that [DDMIM][Cl] and [BMIM][DS] micellar solutions enhance the electrocatalytic performance of VB₁₂ by 10⁶ and 10⁴ times respectively. The presented study is of significant importance in light of some recent reports that have demonstrated the aptness of aqueous SAIL micellar solutions for aqueous phase eco-green electro-detoxification of water insoluble halocarbons.