Published January 2007 | Version v1
Journal article Metadata-only

Phase transformation in the binary section of the UO2-FeO-Fe system

Creators

  • 1. Nauchno-Issledovatel'skij Tekhnologicheskij Inst. im. A.P. Aleksandrova, Sosnovyj Bor, Leningradskaya Obl. (Russian Federation)
  • 2. RAN, Inst. Khimii Silikatov im. I.V. Grebenshchikova, Sankt-Peterburg (Russian Federation)

Description

Phase transformations in the oxide binary section of the UO2-FeO-Fe ternary system were studied. The melting onset point of the UO2-FeO heterogeneous system (1335 ± 5 deg C) was determined and the fusion curve of this system was constructed. The limiting solubility of FeO in the UO2 solid solution was measured. The changes in crystal parameters in formation of the solid solution were determined. Uranium dioxide was found to be insoluble in the wustite phase (FeO)

Abstract (Russian)

Исследованы фазовые превращения в оксидном бинарном разрезе системы UO2-FeO-Fe. Определена температура начала плавления компонентов в гетерогенной системе UO2-FeO (1335±5 град С) и построена кривая плавкости данной системы. Определены предельная растворимость FeO в твердом растворе на основе UO2 и изменения структурных параметров кристаллов при образовании твердого раствора. Показано отсутствие растворимости UO2 в фазе на основе вюстита (FeO)

Additional details

Additional titles

Original title (Russian)
Фазовые превращения в бинарном разрезе системы UO

Publishing Information

Journal Title
Radiokhimiya
Journal Volume
49
Journal Issue
1
Journal Page Range
p. 20-24
ISSN
0033-8311
CODEN
RADKAU

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
38076888
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CONCENTRATION RATIO; DIFFERENTIAL THERMAL ANALYSIS; IRON; IRON OXIDES; LATTICE PARAMETERS; MELTING POINTS; PHASE DIAGRAMS; PHASE STUDIES; SOLID SOLUTIONS; SOLUBILITY; TEMPERATURE RANGE 1000-4000 K; URANIUM DIOXIDE; X-RAY DIFFRACTION
Descriptors DEC
ACTINIDE COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; DIAGRAMS; DIFFRACTION; DIMENSIONLESS NUMBERS; DISPERSIONS; ELEMENTS; HOMOGENEOUS MIXTURES; INFORMATION; IRON COMPOUNDS; METALS; MIXTURES; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SCATTERING; SOLUTIONS; TEMPERATURE RANGE; THERMAL ANALYSIS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; TRANSITION ELEMENTS; TRANSITION TEMPERATURE; URANIUM COMPOUNDS; URANIUM OXIDES

Optional Information

Notes
19 refs., 4 figs., 1 tab.