Published April 2022 | Version v1
Journal article

Pyridine-based conjugated microporous polymers as adsorbents for CO2 uptake via weak supramolecular interaction

  • 1. Jilin Univ, Coll Chem, Changchun 130012, Peoples R (China)
  • 2. Jilin Normal Univ, Minist Educ, Lab Preparat and Applicat Environm Friendly Mat, Changchun 130103, Peoples R (China)
  • 3. Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram and Superfine, Shanghai 200050, Peoples R (China)
  • 4. Changchun Univ Technol, Sch Chem and Biol, Adv Inst Mat Sci, Changchun 130012, Peoples R (China)

Description

Conjugated microporous polymers (CMPs) are a unique class of materials that combine pre-designable pi-conjugation with permanent micro-porosity. Here, two CMPs without pyridine units (CMP-1 and CMP-2) and pyridine-based CMPs (P-CMP-1 and P-CMP-2) were constructed via a pre-designable strategy. Interestingly, the P-CMPs anchored active pyridine groups in the backbone and possessed high micro-porosity. The P-CMPs exhibited high CO2 capture values via weak supramolecular interaction, which are much higher than those of CMPs without pyridine units. (authors)

Additional details

Identifiers

Publishing Information

Journal Title
New Journal of Chemistry
Journal Volume
46
Journal Issue
no.14
Journal Page Range
p. 6394-6397
ISSN
1144-0546