Published September 1992
| Version v1
Journal article
Kinetics of reaction of Np(VI) with H2O2 in tributyl-phosphate
Creators
Description
The reaction of Np(VI) with H2O2 is studied by spectrophotometry in 100% TBP in the range 25-45 degrees C. The reaction rate is first order in Np(VI), increases with increasing water and H2O2 content, and decreases with increasing acid concentration and Np(V) accumulation. The mechanism of the reaction is discussed
Additional details
Publishing Information
- Journal Title
- Radiochemistry (New York)
- Journal Volume
- 34
- Journal Issue
- 1
- Journal Page Range
- p. 98-102.
- ISSN
- 1066-3622
- CODEN
- RDIOEO
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 25013891
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- CHEMICAL REACTION KINETICS; CONCENTRATION RATIO; HYDROGEN PEROXIDE; NEPTUNIUM; OXIDATION; REDUCTION; SPECTROPHOTOMETRY; TBP; WATER
- Descriptors DEC
- ACTINIDES; BUTYL PHOSPHATES; CHEMICAL REACTIONS; ELEMENTS; ESTERS; HYDROGEN COMPOUNDS; KINETICS; METALS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; OXYGEN COMPOUNDS; PEROXIDES; PHOSPHORIC ACID ESTERS; REACTION KINETICS; TRANSURANIUM ELEMENTS
Optional Information
- Notes
- Translated from Radiokhimiya; 34: No. 1, 120-125(Jan-Feb 1992).