Plasma-facilitated modification of pumpkin vine-based biochar and its application for efficient elimination of uranyl from aqueous solution

An acrylic modified pumpkin vine-based biochar (p-PVB-PAA) is synthesized by non-thermal plasma-grafting modification of pumpkin vine-based biochar (PVB) for the removal of uranyl from an aqueous solution. Microscopic characterization reveals that compared to PVB the surface of p-PVB-PAA has more oxygen-containing functional groups by strong chemical bonding and the specific surface area is increased to 275.3 m² g⁻¹ from 3.8 m² g⁻¹. It is found that p-PVB-PAA showed a much higher maximum adsorption capacity for uranyl from aqueous solutions than PVB, which were 207.02 mg g⁻¹ and 67.58 mg g⁻¹ at pH = 5 and 298 K, respectively. Moreover, the adsorption behavior follows a pseudo-second-order kinetics model and the Langmuir adsorption model. Additionally, macroscopic experiments and spectroscopic studies verified that the significantly improved adsorption performance of the p-PVB-PAA is due to surface complexation and electrostatic interactions. Furthermore, the very high removal efficiency and excellent regeneration ability (the percentage of the removal still remained at nearly 90% after five cycles) makes this low-cost, easily obtained, and environmentally friendly material attractive for commercial application. (paper)