Published September 11, 2012 | Version v1
Report

Iron Corrosion Observations: Pu(VI)-Fe Reduction Studies

Description

Iron and Pu Reduction: (1) Very different appearances in iron reaction products were noted depending on pH, brine and initial iron phase; (2) Plutonium was associated with the Fe phases; (3) Green rust was often noted at the higher pH; (4) XANES established the green rust to be an Fe2/3 phase with a bromide center; and (5) This green rust phase was linked to Pu as Pu(IV).

Additional details

Publishing Information

Imprint Pagination
vp.
Report number
LA-UR--12-24638

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
43127839
Subject category
S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS; S54: ENVIRONMENTAL SCIENCES;
Resource subtype / Literary indicator
Non-conventional Literature
Descriptors DEI
BRINES; BROMIDES; CORROSION; IRON; PLUTONIUM
Descriptors DEC
ACTINIDES; BROMINE COMPOUNDS; CHEMICAL REACTIONS; ELEMENTS; HALIDES; HALOGEN COMPOUNDS; METALS; TRANSITION ELEMENTS; TRANSURANIUM ELEMENTS

Optional Information

Contract/Grant/Project number
AC52-06NA25396
Notes
doi 10.2172/1050515
Funding organization
DOE/LANL (United States)