Published March 2018 | Version v1
Journal article Metadata-only

Intramolecular cyclization of lithium 4,4-dimethoxy-1-(perfluoroalkyl)pentane-1,3-dionates on treatment with boron trifluoride diethyl etherate

Creators

  • 1. Ural Branch of the Russian Academy of Sciences, I. Ya. Postovsky Institute of Organic Synthesis (Russian Federation)

Description

Lithium 4,4-dimethoxy-1-(perfluoroalkyl)pentane-1,3-dionates react with BF3•Et2O to give 2-methoxy-2-methyl-5-(perfluoroalkyl)furan-3(2H)-ones in high yields.

Additional details

Identifiers

DOI
10.1007/s11172-018-2099-2;

Publishing Information

Journal Title
Russian Chemical Bulletin
Journal Volume
67
Journal Issue
3
Journal Page Range
p. 497-499
ISSN
1066-5285
CODEN
RCBUEY

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
51025230
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACETALS; BORON FLUORIDES; CYCLIZATION; FURANS; KETONES; LITHIUM COMPOUNDS; PENTANE; YIELDS
Descriptors DEC
ALKALI METAL COMPOUNDS; ALKANES; BORON COMPOUNDS; BORON HALIDES; CHEMICAL REACTIONS; ETHERS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS

Optional Information

Copyright
Copyright (c) 2018 Springer Science+Business Media, LLC, part of Springer Nature