Published June 1978
| Version v1
Journal article
Isotropic and anisotropic nuclear magnetic shielding of 113Cd in cadmiumhalides, cadmiumchalcogenides and in cadmiumcarbonate
Description
The NMR signals of 113Cd have been observed in powder samples of the cadmium halides CdF2, CdCl2, CdBr2.4 H2O, CdI2, of the cadmium chalcogenides CdO, CdS, CdSe, CdTe and of CdCO3. For 113Cd in CdCl2, CdBr2.4 H2O, CdS and in CdSe anisotropies of the nuclear magnetic shielding have been detected. The shielding tensor in these powders is axially symmetric. For the other specimens no anisotropies of the magnetic shielding have been found. The principal values of the magnetic shielding tensor and the shielding constants are given in an atomic reference scale. (orig.)
Abstract (German)
Die NMR-Signale von 113Cd wurden in pulverisierten Proben der Kadmiumhalogenide CdF2, CdCl2, CdBr2.4H2O, CdI2, der Kadmiumchalcogenide CdO, CdS, CdSe, CdTe und von CdCO3 beobachtet. In CdCl2, CdBr2.4H2O, CdS und in CdSe wurden Anisotropien der magnetischen Abschirmung des Kern von 113Cd entdeckt. Der Abschirmungstensor in diesen Proben ist axialsymmetrisch. Bei den anderen Proben wurden keine Anisotropien der magnetischen Abschirmung gefunden. Die grundlegenden Werte des magnetischen Abschirmtensors und die Abschirmungskonstanten werden in einer atomaren Bezugsskala angegeben. (orig.)Additional details
Identifiers
Publishing Information
- Journal Title
- Zeitschrift für Naturforschung A
- Journal Volume
- 33
- Journal Issue
- 6
- Series
- Z. Naturforsch., A.
- Journal Page Range
- 666-671
- ISSN
- 1865-7109
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 9412862
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- CADMIUM BROMIDES; CADMIUM CARBONATES; CADMIUM CHLORIDES; CADMIUM FLUORIDES; CADMIUM IODIDES; CADMIUM OXIDES; CADMIUM SELENIDES; CADMIUM SULFIDES; CADMIUM TELLURIDES; CADMIUM 113; LINE WIDTHS; NUCLEAR MAGNETIC RESONANCE; SHIELDING; TENSORS
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BROMIDES; BROMINE COMPOUNDS; CADMIUM COMPOUNDS; CADMIUM ISOTOPES; CARBON COMPOUNDS; CARBONATES; CHALCOGENIDES; CHLORIDES; CHLORINE COMPOUNDS; EVEN-ODD NUCLEI; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; INORGANIC PHOSPHORS; INTERMEDIATE MASS NUCLEI; IODIDES; IODINE COMPOUNDS; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; MAGNETIC RESONANCE; NUCLEI; OXIDES; OXYGEN COMPOUNDS; PHOSPHORS; RADIOISOTOPES; RESONANCE; SELENIDES; SELENIUM COMPOUNDS; STABLE ISOTOPES; SULFIDES; SULFUR COMPOUNDS; TELLURIDES; TELLURIUM COMPOUNDS; YEARS LIVING RADIOISOTOPES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent