Multiple state of heavy lanthanide filled skutterudites

We discuss multipole properties of filled skutterudites containing heavy lanthanide Ln from a microscopic viewpoint on the basis of a seven-orbital Anderson model. For Ln=Gd, in contrast to naive expectation, quadrupole moments remain in addition to main dipole ones. For Ln=Ho, we find an exotic state governed by octupole moment. For Ln=Tb and Tm, no significant multipole moments appear at low temperatures, while for Ln=Dy, Er, and Yb, dipole and higher-order multipoles are dominant. We briefly discuss possible relevance of these multipole states with actual materials. (author)