Published May 2005 | Version v1
Journal article Metadata-only

Catalytic decomposition of inorganic peroxide compounds

Creators

  • 1. RAN, Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova, Moscow (Russian Federation)
  • 2. Moskovskij Pedagogicheskij Gosudarstvennyj Univ., Moscow (Russian Federation)

Description

Decomposition of aqueous solutions of coordination peroxide boron and tin compounds in alkaline medium is studied at pH 8-13 under nickel(II) sulfate effect. It is shown that decomposition of sodium peroxoborate could take place in oscillating regime. Scheme of mechanism of catalytic decomposition of peroxide compounds is proposed

Abstract (Russian)

Изучено разложение водных растворов координационных перикисных соединений бора и олова в щелочной среде при pH 8-13 под действием сульфата нике (II). Показано, что разложение пероксобората натрия может протекать в колебательном режиме. Предложена схема механизма каталитического разложения перикисных соединений

Additional details

Additional titles

Original title (Russian)
Каталитическое разложение неорганических перикисных соединений

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
50
Journal Issue
5
Journal Page Range
p. 763-768
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36100421
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; BORON COMPOUNDS; CATALYSIS; CHEMICAL REACTION KINETICS; DECOMPOSITION; NICKEL SULFATES; PEROXIDES; SODIUM COMPOUNDS
Descriptors DEC
ALKALI METAL COMPOUNDS; CHEMICAL REACTIONS; DISPERSIONS; HOMOGENEOUS MIXTURES; KINETICS; MIXTURES; NICKEL COMPOUNDS; OXYGEN COMPOUNDS; REACTION KINETICS; SOLUTIONS; SULFATES; SULFUR COMPOUNDS; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
13 refs.; 10 figs.