Published November 2017 | Version v1
Journal article Metadata-only

Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands

Creators

  • 1. Yuncheng University, Department of Applied Chemistry (China)
  • 2. Harbin Institute of Technology, MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering (China)

Description

A copper complex with V-shaped ligands, [(L1)Cu2Cl2]n (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/c with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R1 = 0.0681, and wR2 = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.

Additional details

Identifiers

DOI
10.1134/S1063774517060268;

Publishing Information

Journal Title
Crystallography Reports
Journal Volume
62
Journal Issue
6
Journal Page Range
p. 881-884
ISSN
1063-7745
CODEN
CYSTE3

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
50001190
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AROMATICS; CHLORIDES; COPPER COMPLEXES; CRYSTALS; HYDROGEN; INFRARED SPECTRA; LAYERS; LIGANDS; MONOCLINIC LATTICES; SYNTHESIS; X-RAY DIFFRACTION
Descriptors DEC
CHLORINE COMPOUNDS; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; ELEMENTS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; NONMETALS; ORGANIC COMPOUNDS; SCATTERING; SPECTRA; THREE-DIMENSIONAL LATTICES; TRANSITION ELEMENT COMPLEXES

Optional Information

Copyright
Copyright (c) 2017 Pleiades Publishing, Inc.