Published November 2010
| Version v1
Journal article
Electronic structure of two phosphorus compounds
Creators
- 1. Charles Sturt University, POB 883, Orange NSW 2800 (Australia)
- 2. Physical Chemistry Division, 'R. Boskovic' Institute, HR-10000 Zagreb (Croatia)
Description
The electronic structures of tri-2-furanyl-phosphine (I) and 1,2-bis(dimethoxyphosphoryl)benzene (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and quantum chemical calculations. Their electronic structures are discussed in the framework of their chemical properties and practical applications with special reference to the extent of intramolecular interactions. We have also rationalized the observed increased shielding of phosphorus in 31P NMR spectra of TFP.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.elspec.2010.06.006Additional details
Identifiers
- DOI
- 10.1016/j.elspec.2010.06.006;
- PII
- S0368-2048(10)00138-6;
Publishing Information
- Journal Title
- Journal of Electron Spectroscopy and Related Phenomena
- Journal Volume
- 182
- Journal Issue
- 1-2
- Journal Page Range
- p. 76-80
- ISSN
- 0368-2048
- CODEN
- JESRAW
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 42058191
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- CHEMICAL PROPERTIES; ELECTRONIC STRUCTURE; NMR SPECTRA; PHOSPHINES; PHOSPHORUS 31; PHOTOELECTRON SPECTROSCOPY
- Descriptors DEC
- ELECTRON SPECTROSCOPY; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; PHOSPHORUS COMPOUNDS; PHOSPHORUS ISOTOPES; SPECTRA; SPECTROSCOPY; STABLE ISOTOPES
Optional Information
- Copyright
- Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.