Volumetric and acoustic properties of some sodium sulfonamides in dilute aqueous solutions at several temperatures
- 1. Grupo de Investigaciones Farmacéutico-Fisicoquímicas, Departamento de Farmacia, Facultad de Ciencias, Universidad Nacional de Colombia – Sede Bogotá, Cra. 30 No. 45-03, Bogotá D.C. (Colombia)
- 2. Grupo de Termodinámica de Soluciones, Departamento de Química, Facultad de Ciencias, Universidad de los Andes, Cra 1 No. 18A-12, Bogotá D.C. (Colombia)
Description
Highlights: • The standard (infinite dilution) molar properties were determined. • Three sodium sulfonamides were studied in aqueous solutions. • The dependence of the standard molar properties with temperature were studied. Densities and speed of sound of dilute aqueous solutions of three sodium sulfonamides structurally-related, namely, sodium sulfadiazine (NaSD), sodium sulfamerazine (NaSMR) and sodium sulfamethazine (NaSMT) were measured as a function of molal concentration at various temperatures (278.15–308.15) K. Standard molar quantities and related properties were calculated and the results were interpreted in terms of structural effects, and solute-solvent interactions. Results suggest that these sulfonamides are acting as structure makers of the water-structure.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2017.11.007Additional details
Identifiers
- DOI
- 10.1016/j.jct.2017.11.007;
- PII
- S0021961417303993;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 118
- Journal Page Range
- p. 159-164
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 53013018
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- APPARENT MOLAL VOLUME; AQUEOUS SOLUTIONS; COMPRESSIBILITY; CONCENTRATION RATIO; DENSITY; DILUTION; INTERACTIONS; PYRIMIDINES; SODIUM; SOLUTES; SOLVENTS; STANDARDS; SULFONAMIDES; WATER
- Descriptors DEC
- ALKALI METALS; AMIDES; ANTI-INFECTIVE AGENTS; ANTIMICROBIAL AGENTS; AZINES; DIMENSIONLESS NUMBERS; DISPERSIONS; DRUGS; ELEMENTS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; MECHANICAL PROPERTIES; METALS; MIXTURES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SOLUTIONS
Optional Information
- Copyright
- Copyright (c) 2017 Elsevier Ltd.