Published March 2018 | Version v1
Journal article

Volumetric and acoustic properties of some sodium sulfonamides in dilute aqueous solutions at several temperatures

  • 1. Grupo de Investigaciones Farmacéutico-Fisicoquímicas, Departamento de Farmacia, Facultad de Ciencias, Universidad Nacional de Colombia – Sede Bogotá, Cra. 30 No. 45-03, Bogotá D.C. (Colombia)
  • 2. Grupo de Termodinámica de Soluciones, Departamento de Química, Facultad de Ciencias, Universidad de los Andes, Cra 1 No. 18A-12, Bogotá D.C. (Colombia)

Description

Highlights: • The standard (infinite dilution) molar properties were determined. • Three sodium sulfonamides were studied in aqueous solutions. • The dependence of the standard molar properties with temperature were studied. Densities and speed of sound of dilute aqueous solutions of three sodium sulfonamides structurally-related, namely, sodium sulfadiazine (NaSD), sodium sulfamerazine (NaSMR) and sodium sulfamethazine (NaSMT) were measured as a function of molal concentration at various temperatures (278.15–308.15) K. Standard molar quantities and related properties were calculated and the results were interpreted in terms of structural effects, and solute-solvent interactions. Results suggest that these sulfonamides are acting as structure makers of the water-structure.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2017.11.007

Additional details

Identifiers

DOI
10.1016/j.jct.2017.11.007;
PII
S0021961417303993;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
118
Journal Page Range
p. 159-164
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2017 Elsevier Ltd.