Published April 20, 1998 | Version v1
Journal article Metadata-only

B4 tetrahedra for aluminum atoms - a surprising substitution in τ-borides Ni20Al3B6 and Ni20AlB14

Creators

  • 1. Freiburg Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie

Description

The highly symmetric title compound contains a Ni atom that is tetrahedrally coordinated by four alkylindium(I) ligands InC(SiMe3)3. The ligand InR is isolobal with carbon monoxide, and the product is thus a remarkable addition to the class of [Ni(CO)4] analogues. (orig.)

Additional details

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Volume
37
Journal Issue
7
Journal Page Range
p. 935-938
ISSN
1433-7851

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
30003310
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CRYSTAL STRUCTURE; INDIUM COMPOUNDS; MOLECULAR STRUCTURE; NICKEL COMPOUNDS; ORGANOMETALLIC COMPOUNDS; SOLID CLUSTERS; SYNTHESIS
Descriptors DEC
ORGANIC COMPOUNDS; TRANSITION ELEMENT COMPOUNDS