Published January 25, 1985
| Version v1
Journal article
Trapping free radicals formed in the reaction of ozone with simple olefins using 2,6-Di-tert-butyl-4-cresol (BHT)
Description
Free radicals are detected from the ozonation of a series of olefins using a BHT trapping technique. We have determined the structure of the adduct when 3,3-dimethylbutene (tert-butylethylene) is ozonated at -780C and then warmed in the presence of BHT. The adduct can be rationalized as arising from trapping tert-butylperoxyl radicals by BHT to give 2,6-di-tert-butyl-4-(tert-butylperoxy)-4-methyl-2,5-cyclohexadienone. 17 references, 4 figures, 4 tables
Additional details
Additional titles
- Augmented title (English)
- 3,3-dimethylbutene
Publishing Information
- Journal Title
- J. Org. Chem.
- Journal Volume
- 50
- Journal Issue
- 2
- Series
- J. Org. Chem.
- Journal Page Range
- 185-189
- ISSN
- 0022-3263
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 16080102
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; ADDUCTS; ALKENES; CHEMICAL REACTION YIELD; CHEMICAL REACTIONS; CHEMISORPTION; CRESOLS; ELECTRONIC STRUCTURE; EXPERIMENTAL DATA; INFRARED SPECTRA; LIQUID COLUMN CHROMATOGRAPHY; LOW TEMPERATURE; MASS SPECTROSCOPY; NMR SPECTRA; ORGANIC SOLVENTS; OXYGEN; OZONE; PENTANE; PEROXY RADICALS; REACTION INTERMEDIATES; STRUCTURAL CHEMICAL ANALYSIS; ULTRAVIOLET SPECTRA
- Descriptors DEC
- ALKANES; AROMATICS; CHROMATOGRAPHY; DATA; ELEMENTS; HYDROCARBONS; HYDROXY COMPOUNDS; INFORMATION; NONAQUEOUS SOLVENTS; NONMETALS; NUMERICAL DATA; ORGANIC COMPOUNDS; PHENOLS; RADICALS; SEPARATION PROCESSES; SOLVENTS; SPECTRA; SPECTROSCOPY