Published September 8, 2004
| Version v1
Journal article
Reconciling semiclassical and Bohmian mechanics. I. Stationary states
Creators
- 1. Department of Chemistry and Biochemistry, and Department of Physics, Texas Tech University, Lubbock, Texas 79409-1061 (United States)
Description
The semiclassical method is characterized by finite forces and smooth, well-behaved trajectories, but also by multivalued representational functions that are ill behaved at caustics. In contrast, quantum trajectory methods - based on Bohmian mechanics (quantum hydrodynamics) - are characterized by divergent forces and erratic trajectories near nodes, but also well-behaved, single-valued representational functions. In this paper, we unify these two approaches into a single method that captures the best features of both, and in addition, satisfies the correspondence principle. Stationary eigenstates in one degree of freedom are the primary focus, but more general applications are also anticipated
Additional details
Identifiers
- DOI
- 10.1063/1.1775766;
- arXiv
- arXiv:0802.3472v1;
Publishing Information
- Journal Title
- Journal of Chemical Physics
- Journal Volume
- 121
- Journal Issue
- 10
- Journal Page Range
- p. 4501-4515
- ISSN
- 0021-9606
- CODEN
- JCPSA6
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 36002469
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- DEGREES OF FREEDOM; EIGENFUNCTIONS; EIGENSTATES; EIGENVALUES; HYDRODYNAMICS; QUANTUM MECHANICS; TRAJECTORIES
- Descriptors DEC
- FLUID MECHANICS; FUNCTIONS; MECHANICS
Optional Information
- Notes
- (c) 2004 American Institute of Physics.