Published March 31, 1984
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Study of intermediates from transition metal excited-state electron-transfer reactions. Progress report, April 1, 1983-March 31, 1984
Description
In our study of intermediates from excited-state electron-transfer reactions, we have focused our attention during the past year on MV+., the reduced methyl viologen radical cation, which is a precursor to the formation of H2 in the photosensitized reduction of water. Through the use of photochemical and radiation chemical techniques, we have examined the efficiency of interaction of MV+. with colloidal Pt, the stability of MV+. as a function of pH, the quantum yield of formation of MV+. in the Ru(bpy)32+/MV2+/EDTA system, and the formation of photoactive charge-transfer complexes between MV2+ and sacrificial electron donors
Availability note (English)
MF available from INIS under the Report Number; Available from NTIS, PC A02/MF A01; 1 as DE84008587.
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Additional details
Additional titles
- Augmented title (English)
- Methyl viologen radical cation
Publishing Information
- Imprint Pagination
- 7 p.
- Report number
- DOE/ER/10971--2
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 15063556
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Progress Report
- Descriptors DEI
- BIPYRIDINES; CATALYSIS; CATIONS; COMPLEXES; EDTA; ELECTRON TRANSFER; HYDROGEN; PHOTOCHEMISTRY; PLATINUM; PRODUCTION; RADICALS; REDUCTION; RESEARCH PROGRAMS; RUTHENIUM COMPLEXES
- Descriptors DEC
- AMINO ACIDS; AZINES; CARBOXYLIC ACIDS; CHARGED PARTICLES; CHELATING AGENTS; CHEMICAL REACTIONS; CHEMISTRY; ELEMENTS; HETEROCYCLIC COMPOUNDS; IONS; METALS; NONMETALS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PLATINUM METALS; PYRIDINES; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS