Published February 2010
| Version v1
Journal article
Volumetric, acoustic, and viscometric studies of molecular interactions in binary mixtures of diethylene glycol monomethyl ether with 1-alkanols at temperatures from (293.15 to 308.15) K
- 1. Department of Chemistry, Kurukshetra University, Kurukshetra 136119 (India)
Description
In this work, densities ρ, speeds of sound u, and viscosities η, have been measured over the whole composition range for the binary mixtures of diethylene glycol monomethyl ether (DEGMME), CH3(OCH2CH2)2OH with 1-hexanol, CH3(CH2)5OH, 1-octanol, CH3(CH2)7OH, and 1-decanol, CH3(CH2)9OH at T = (293.15, 298.15, 303.15, and 308.15) K along with the properties of the pure components. By using the experimental values of ρ, u, and η, excess molar volume, VmE, deviations in viscosity, Δη, isentropic compressibility κS, deviations in isentropic compressibility ΔκS, deviations of the speed of sound Δu, have been calculated. The viscosity results have also been analysed in terms of some semi-empirical equations.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2009.08.009Additional details
Identifiers
- DOI
- 10.1016/j.jct.2009.08.009;
- PII
- S0021-9614(09)00216-X;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 42
- Journal Issue
- 2
- Journal Page Range
- p. 234-243
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 41076816
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALCOHOLS; BINARY MIXTURES; COMPRESSIBILITY; DENSITY; EQUATIONS; ETHERS; GLYCOLS; INTERACTIONS; ISENTROPIC PROCESSES; SOUND WAVES; TEMPERATURE RANGE 0273-0400 K; VELOCITY; VISCOSITY
- Descriptors DEC
- ALCOHOLS; DISPERSIONS; HYDROXY COMPOUNDS; MECHANICAL PROPERTIES; MIXTURES; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.