Published February 2010 | Version v1
Journal article

Volumetric, acoustic, and viscometric studies of molecular interactions in binary mixtures of diethylene glycol monomethyl ether with 1-alkanols at temperatures from (293.15 to 308.15) K

  • 1. Department of Chemistry, Kurukshetra University, Kurukshetra 136119 (India)

Description

In this work, densities ρ, speeds of sound u, and viscosities η, have been measured over the whole composition range for the binary mixtures of diethylene glycol monomethyl ether (DEGMME), CH3(OCH2CH2)2OH with 1-hexanol, CH3(CH2)5OH, 1-octanol, CH3(CH2)7OH, and 1-decanol, CH3(CH2)9OH at T = (293.15, 298.15, 303.15, and 308.15) K along with the properties of the pure components. By using the experimental values of ρ, u, and η, excess molar volume, VmE, deviations in viscosity, Δη, isentropic compressibility κS, deviations in isentropic compressibility ΔκS, deviations of the speed of sound Δu, have been calculated. The viscosity results have also been analysed in terms of some semi-empirical equations.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2009.08.009

Additional details

Identifiers

DOI
10.1016/j.jct.2009.08.009;
PII
S0021-9614(09)00216-X;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
42
Journal Issue
2
Journal Page Range
p. 234-243
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.