Geochemical studies of the river-estuarine systems of Krishna and Godavari

During summer season, the Krishna river waters are enriched in major cations Na, K, Mg, Ca and Si by a factor of 1.2-1.9, in U by a factor of 3 and in delta D by 14.2per cent compared to those of Godavari. The high delta D of Krishna river waters (+ 1.6per cent) over those of Godavari (- 12.6per cent) indicate relatively more evaporation of the former by 15per cent. The uranium concentrations of Krishna waters at Vijayawada is 2.6 μ/l which decreases to 1.6 μ/l at Puligadda which is approx. 100 km downstream, whereas the 234U/238U activity ratio at both places is identical, 1.65 +- 0.03 suggesting authigenic removal of U in regions downstream of Vijayawada. Also, U does not appear to behave conservatively in the Krishna estuary as has been its behaviour in other Indian and some world rivers; there is removal of U from the Krishna estuarine waters. The major cations and delta D behave conservatively in both Krishna and Godavari estuaries. Si behaves almost conservatively in the Krishna estuary whereas in the Godavari estuary there is about 15per cent Si removal. The fluxes of all the measured constituents from Krishna and Godavari to the Bay of Bengal during the non-monsoon period are calculated. The clay, silt and and sand fractions as well as the Al, Fe, Mn, Cr and Ni concentrations of the clay fractions were determined in eight Krishna estuarine sediments and the results are discussed. The non-monsoonal clay, Al, Fe, Mn, Cr and Ni fluxes from Krishna river to the Bay of Bengal are also estimated. (author)