Published 2015
| Version v1
Book
Determination of standard molar Gibbs energy of formation of Sm6UO12(s)
Creators
- 1. Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai (India)
- 2. Product Development Division, Bhabha Atomic Research Centre, Mumbai (India)
Description
The standard molar Gibbs energies of formation of Sm6UO12(s) have been measured using an oxygen concentration cell with yttria stabilized zirconia as solid electrolyte. ΔfGom(T) for Sm6UO12(s) has been calculated using the measured and required thermodynamic data from the literature. The calculated Gibbs energy expression in the temperature range 899 to 1127 K can be given as: ΔfGom(Nd6UO12, s,T)/(±2.3) kJ∙ mol-1 = -6681 +1.099 (T/K) (899-1127 K)(T/K). (author)
Additional details
Publishing Information
- Publisher
- Board of Research in Nuclear Sciences
- Imprint Place
- Mumbai (India)
- Imprint Title
- Proceedings of the twelfth DAE-BRNS national symposium on nuclear and radiochemistry
- Imprint Pagination
- 700 p.
- Journal Page Range
- p. 240-241
Conference
- Title
- 12. DAE-BRNS national symposium on nuclear and radiochemistry
- Acronym
- NUCAR-2015
- Dates
- 9-13 Feb 2015
- Place
- Mumbai (India)
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 46089636
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- FORMATION FREE ENTHALPY; SAMARIUM OXIDES; SOLID ELECTROLYTES; URANIUM OXIDES; X-RAY DIFFRACTION; ZIRCONIUM OXIDES
- Descriptors DEC
- ACTINIDE COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; DIFFRACTION; ELECTROLYTES; ENERGY; FREE ENTHALPY; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; RARE EARTH COMPOUNDS; SAMARIUM COMPOUNDS; SCATTERING; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; URANIUM COMPOUNDS; ZIRCONIUM COMPOUNDS
Optional Information
- Notes
- 4 refs., 2 figs.