Published March 2018 | Version v1
Journal article Metadata-only

Enthalpy of formation of ye'elimite and ternesite

Creators

  • 1. University of Aberdeen, Department of Chemistry (United Kingdom)
  • 2. University of Sheffield, Department of Materials Science and Engineering (United Kingdom)

Description

Calcium sulfoaluminate clinkers containing ye'elimite (Ca4Al6O12(SO4)) and ternesite (Ca5(SiO4)2SO4) are being widely investigated as components of calcium sulfoaluminate cement clinkers. These may become low energy replacements for Portland cement. Conditional thermodynamic data for ye'elimite and ternesite (enthalpy of formation) have been determined experimentally using a combination of techniques: isothermal conduction calorimetry, X-ray powder diffraction and thermogravimetric analysis. The enthalpies of formation of ye'elimite and ternesite at 25 °C were determined to be − 8523 and − 5993 kJ mol−1, respectively.

Additional details

Identifiers

DOI
10.1007/s10973-017-6751-0;

Publishing Information

Journal Title
Journal of Thermal Analysis and Calorimetry
Journal Volume
131
Journal Issue
3
Journal Page Range
p. 2345-2359
ISSN
1388-6150

INIS

Country of Publication
Hungary
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
50019363
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
ALUMINATES; CALCIUM COMPOUNDS; CALORIMETRY; SILICATES; THERMAL GRAVIMETRIC ANALYSIS; THERMODYNAMICS; X-RAY DIFFRACTION
Descriptors DEC
ALKALINE EARTH METAL COMPOUNDS; ALUMINIUM COMPOUNDS; CHEMICAL ANALYSIS; COHERENT SCATTERING; DIFFRACTION; GRAVIMETRIC ANALYSIS; OXYGEN COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; SILICON COMPOUNDS; THERMAL ANALYSIS

Optional Information

Copyright
Copyright (c) 2017 The Author(s)