Published September 15, 2021 | Version v1
Journal article

Correct scaling of the correlation length from a theory for concentrated electrolytes

  • 1. Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warszawa (Poland)
  • 2. Institute for Condensed Matter Physics, National Academy of Sciences of Ukraine, Lviv (Ukraine)

Description

Self-consistent theory for concentrated electrolytes is developed. Oscillatory decay of the charge–charge correlation function with the decay length that shows perfect agreement with the experimentally discovered and so far unexplained scaling is obtained. For the density–density correlations, monotonic asymptotic decay with the decay length comparable with the decay length of the charge correlations is found. We show that the correlation lengths in concentrated electrolytes depend crucially on the local variance of the charge density. (letter)

Availability note (English)

Available from http://dx.doi.org/10.1088/1361-648X/ac0f9e

Additional details

Identifiers

Publishing Information

Journal Title
Journal of Physics. Condensed Matter
Journal Volume
33
Journal Issue
37
Journal Page Range
[5 p.]
ISSN
0953-8984
CODEN
JCOMEL

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
53098452
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
ASYMPTOTIC SOLUTIONS; CHARGE DENSITY; ELECTROLYTES
Descriptors DEC
MATHEMATICAL SOLUTIONS