Published September 15, 2021
| Version v1
Journal article
Correct scaling of the correlation length from a theory for concentrated electrolytes
Creators
- 1. Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warszawa (Poland)
- 2. Institute for Condensed Matter Physics, National Academy of Sciences of Ukraine, Lviv (Ukraine)
Description
Self-consistent theory for concentrated electrolytes is developed. Oscillatory decay of the charge–charge correlation function with the decay length that shows perfect agreement with the experimentally discovered and so far unexplained scaling is obtained. For the density–density correlations, monotonic asymptotic decay with the decay length comparable with the decay length of the charge correlations is found. We show that the correlation lengths in concentrated electrolytes depend crucially on the local variance of the charge density. (letter)
Availability note (English)
Available from http://dx.doi.org/10.1088/1361-648X/ac0f9eAdditional details
Identifiers
Publishing Information
- Journal Title
- Journal of Physics. Condensed Matter
- Journal Volume
- 33
- Journal Issue
- 37
- Journal Page Range
- [5 p.]
- ISSN
- 0953-8984
- CODEN
- JCOMEL
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 53098452
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- ASYMPTOTIC SOLUTIONS; CHARGE DENSITY; ELECTROLYTES
- Descriptors DEC
- MATHEMATICAL SOLUTIONS