Published July 1, 1982 | Version v1
Journal article Metadata-only

Observation of electron paramagnetic resonance in organometallic compounds of uranium

Creators

  • 1. CEA Centre d'Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette (France). Dept. de Physico-Chimie

Description

The trivalency of uranium can be easily established in frozen solution by epr. The broad resonance signal observed at low temperature (7 K) with g = 3.5 appears as characteristic of the trivalent state in UZrF7(powder), U(C5H5)3. tetrahydrofuran, and U(C5H5)3.CH3-(frozen solutions)

Additional details

Additional titles

Original title (French)
Observation de la resonance paramagnetique electronique dans les composes organometalliques d'uranium

Publishing Information

Journal Title
Can. J. Chem.
Journal Volume
60
Journal Issue
13
Series
Can. J. Chem.
Journal Page Range
1751-1753
ISSN
0008-4042

INIS

Country of Publication
Canada
Country of Input or Organization
Canada
INIS RN
14760749
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ELECTRON SPIN RESONANCE; ORGANOMETALLIC COMPOUNDS; ULTRALOW TEMPERATURE; URANIUM FLUORIDES; VALENCE
Descriptors DEC
ACTINIDE COMPOUNDS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; RESONANCE; URANIUM COMPOUNDS