Published November 2017 | Version v1
Journal article Metadata-only

The synthesis and comparative characterization of three novel electroactive iminoboronates containing ferrocene

Creators

  • 1. Masaryk University, Department of Biochemistry, Faculty of Science (Czech Republic)
  • 2. Masaryk University, Central European Institute of Technology (Czech Republic)

Description

Along our way towards the advanced saccharide-sensitive probes, three novel electroactive iminoboronate regioisomers of [(ferrocenylimino)methyl]phenylboronic acid have been synthesized. The ortho, meta, and para regioisomers were characterized structurally by NMR, MS, FT-IR, UV/Vis and their electrochemical behavior in aqueous solution was studied using cyclic voltammetry. The obtained results confirmed different behavior of the ortho isomer due to an interaction of boronic acid moiety with the proximate imine group of the iminoferrocenyl residue. Graphical abstract: .

Additional details

Identifiers

DOI
10.1007/s00706-017-2028-3;

Publishing Information

Journal Title
Monatshefte fuer Chemie
Journal Volume
148
Journal Issue
11
Journal Page Range
p. 1953-1958
ISSN
0026-9247
CODEN
MOCHAP

Conference

Title
16. workshop of Physical Chemists and Electrochemists (WOPCD)
Dates
6-7 Jun 2016
Place
Brno (Czech Republic)

INIS

Country of Publication
Austria
Country of Input or Organization
Austria
INIS RN
49086364
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S77: NANOSCIENCE AND NANOTECHNOLOGY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
AQUEOUS SOLUTIONS; BORONIC ACIDS; ELECTROCHEMISTRY; FERROCENE; FOURIER TRANSFORMATION; IMINES; INFRARED SPECTRA; ISOMERS; NUCLEAR MAGNETIC RESONANCE; RESIDUES; SACCHARIDES; VOLTAMETRY
Descriptors DEC
BORON COMPOUNDS; CARBOHYDRATES; CHEMISTRY; COMPLEXES; DIENES; DISPERSIONS; HOMOGENEOUS MIXTURES; HYDROCARBONS; INTEGRAL TRANSFORMATIONS; IRON COMPLEXES; MAGNETIC RESONANCE; MIXTURES; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; POLYENES; RESONANCE; SOLUTIONS; SPECTRA; TRANSFORMATIONS; TRANSITION ELEMENT COMPLEXES

Optional Information

Copyright
Copyright (c) 2017 Springer-Verlag GmbH Austria