Published February 2007 | Version v1
Journal article

Compressed liquid densities of 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa

  • 1. Laboratorio de Termodinamica, ESIQIE, Instituto Politecnico Nacional, Edif. Z, Secc. 6, 1ER Piso, UPALM, C.P. 07738, Mexico, D.F. (Mexico)

Description

(p, ρ, T) properties were determined in liquid phase for 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa using a vibrating tube densimeter. The uncertainty is estimated to be lower than ±0.2 kg . m-3 for the experimental densities. Nitrogen and water were used as reference fluids for the calibration of the vibrating tube densimeter. Experimental densities of 1-butanol and 2-butanol were correlated with a short empirical equation and the 11-parameter Benedict-Webb-Rubin-Starling equation of state (BWRS EoS) using a least square optimization. Statistical values to evaluate the different correlations were reported. Published densities of 1-butanol and 2-butanol are compared with values calculated with the BWRS EoS using the parameters obtained in this work. The experimental data determined here are also compared with available correlations for 1-butanol and 2-butanol

Additional details

Identifiers

DOI
10.1016/j.jct.2006.07.009;
PII
S0021-9614(06)00157-1;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
39
Journal Issue
2
Journal Page Range
p. 254-260
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.