Compressed liquid densities of 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa
- 1. Laboratorio de Termodinamica, ESIQIE, Instituto Politecnico Nacional, Edif. Z, Secc. 6, 1ER Piso, UPALM, C.P. 07738, Mexico, D.F. (Mexico)
Description
(p, ρ, T) properties were determined in liquid phase for 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa using a vibrating tube densimeter. The uncertainty is estimated to be lower than ±0.2 kg . m-3 for the experimental densities. Nitrogen and water were used as reference fluids for the calibration of the vibrating tube densimeter. Experimental densities of 1-butanol and 2-butanol were correlated with a short empirical equation and the 11-parameter Benedict-Webb-Rubin-Starling equation of state (BWRS EoS) using a least square optimization. Statistical values to evaluate the different correlations were reported. Published densities of 1-butanol and 2-butanol are compared with values calculated with the BWRS EoS using the parameters obtained in this work. The experimental data determined here are also compared with available correlations for 1-butanol and 2-butanol
Additional details
Identifiers
- DOI
- 10.1016/j.jct.2006.07.009;
- PII
- S0021-9614(06)00157-1;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 39
- Journal Issue
- 2
- Journal Page Range
- p. 254-260
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 39036975
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BUTANOLS; CALIBRATION; DENSIMETERS; DENSITY; EQUATIONS OF STATE; EXPERIMENTAL DATA; LEAST SQUARE FIT; LIQUIDS; NITROGEN; OPTIMIZATION; PRESSURE RANGE MEGA PA 10-100; TEMPERATURE RANGE 0273-0400 K
- Descriptors DEC
- ALCOHOLS; DATA; ELEMENTS; EQUATIONS; FLUIDS; HYDROXY COMPOUNDS; INFORMATION; MATHEMATICAL SOLUTIONS; MAXIMUM-LIKELIHOOD FIT; MEASURING INSTRUMENTS; NONMETALS; NUMERICAL DATA; NUMERICAL SOLUTION; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; PRESSURE RANGE; PRESSURE RANGE MEGA PA; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.