Published November 2018 | Version v1
Journal article Metadata-only

Cation-cation interaction between NpVO2+ and Li+ in a concentrated LiCl solution

Creators

  • 1. Osaka University, Graduate School of Engineering, Suita, Osaka (Japan)
  • 2. Kyoto University, Research Reactor Institute, Kumatori, Osaka (Japan)

Description

Coordination circumstance of neptunyl ion in concentrated LiCl, CsCl, CaCl2, and BaCl2 solutions was analyzed by Raman spectrometry. The symmetric stretch (ν1) mode of NpVO2+ and NpVIO22+, and the asymmetric stretch (ν3) mode of NpVO2+ were found. The high Raman intensity of the ν3 mode found for the concentrated LiCl system demonstrated that the cation-cation interaction (CCI) between NpVO2+ and Li+ occurs. The CCI was found to be stronger for the solvent alkali and alkaline earth cations having larger polarizing power. (author)

Availability note (English)

Available from http://dx.doi.org/10.15669/pnst.5.41

Additional details

Identifiers

DOI
10.15669/pnst.5.41;

Publishing Information

Journal Title
Progress in Nuclear Science and Technology
Journal Volume
5
Journal Page Range
p. 41-43
ISSN
2185-4823

Conference

Title
International conference on science and technology of actinide and transactinide elements
Acronym
Actinides 2017
Dates
9-14 Jul 2017
Place
Sendai, Miyagi (Japan)

INIS

Country of Publication
Japan
Country of Input or Organization
Japan
INIS RN
50023732
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ALKALINE EARTH ISOTOPES; AQUEOUS SOLUTIONS; CATIONS; EQUILIBRIUM; HEAVY NUCLEI; LIGANDS; LITHIUM CHLORIDES; MATERIAL SUBSTITUTION; NEPTUNIUM COMPLEXES; NEPTUNIUM IONS; RADIOACTIVITY; RAMAN EFFECT; RAMAN SPECTRA; RAMAN SPECTROSCOPY; REDOX REACTIONS
Descriptors DEC
ACTINIDE COMPLEXES; ALKALI METAL COMPOUNDS; CHARGED PARTICLES; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; IONS; ISOTOPES; LASER SPECTROSCOPY; LITHIUM COMPOUNDS; LITHIUM HALIDES; MIXTURES; NUCLEI; SOLUTIONS; SPECTRA; SPECTROSCOPY; TRANSURANIUM COMPLEXES

Optional Information

Notes
11 refs., 4 figs.