Published June 1989 | Version v1
Journal article Metadata-only

Synthesis of zinc borohydride and its derivatives by mechanoactivation of alkali metal borohydride mixtures with zinc chloride

Creators

  • 1. AN SSSR, Novosibirsk (USSR). Inst. Neorganicheskoj Khimii
  • 2. AN SSSR, Moscow (USSR). Inst. Obshchej i Neorganicheskoj Khimii

Description

By the methods of chemical analysis, DTA and X-ray phase analysis and IR spectroscopy products of ZnCl2 reaction with MBH4 (M = Li, Na, K) after mechanic activation of the initial mixture have been investigated. It is shown that zinc chloride interacts with alkali metal borohydrides already at room temperature. As a result of the reaction zinc borohydride or its complexes with MBH4 are formed. Zinc borohydride and its complexes are isolated from mixture by means of dissolving in benzene or ethyl ether

Additional details

Additional titles

Original title (Russian)
Синтез борогидрида цинка и его производных механоактивацией смесей борогидридов щелочных металлов с хлоридом цинка
Augmented title (English)
Alkali metals: Li, Na, K

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
34
Journal Issue
6
Series
Zh. Neorg. Khim.
Journal Page Range
1430-1434
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
21013321
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKALI METAL COMPOUNDS; BINARY MIXTURES; BOROHYDRIDES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTIONS; INFRARED SPECTRA; LATTICE PARAMETERS; ZINC CHLORIDES; ZINC COMPLEXES
Descriptors DEC
BORON COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; MIXTURES; SPECTRA; SYNTHESIS; ZINC COMPOUNDS