Published July 2016
| Version v1
Journal article
Production of complex rubidium and cesium hydrogen sulfate‒phosphates
- 1. Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)
- 2. Lobachevsky State University of Nizhny Novgorod (Russian Federation)
Description
The solubility in the CsH2PO4‒CsHSO4‒H2O system at different temperatures (25, 50, and 75°C) is studied and the phase equilibria in the Rb3H(SO4)2‒RbH2PO4‒H2O system under isothermal conditions (at 25°C) are analyzed. The temperature and concentration conditions for forming Rb2(HSO4)(H2PO4), Rb4(HSO4)3(H2PO4), Cs4(HSO4)3(H2PO4), Cs3(HSO4)2(H2PO4), Cs2(HSO4)(H2PO4), and Cs6H(HSO4)3(H2PO4)4 compounds (the latter has been obtained for the first time) are determined. The conditions for growing large single crystals of complex acid rubidium and cesium salts are found.
Additional details
Identifiers
Publishing Information
- Journal Title
- Crystallography Reports
- Journal Volume
- 61
- Journal Issue
- 4
- Journal Page Range
- p. 675-681
- ISSN
- 1063-7745
- CODEN
- CYSTE3
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 48094027
- Subject category
- S36: MATERIALS SCIENCE; S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- CARBON SULFIDES; CESIUM PHOSPHATES; CRYSTAL GROWTH; HYDROGEN PHOSPHATES; HYDROGEN SULFATES; MONOCRYSTALS; RUBIDIUM PHOSPHATES; RUBIDIUM SULFATES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CARBON COMPOUNDS; CESIUM COMPOUNDS; CHALCOGENIDES; CRYSTALS; HYDROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHATES; PHOSPHORUS COMPOUNDS; RUBIDIUM COMPOUNDS; SULFATES; SULFIDES; SULFUR COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2016 Pleiades Publishing, Inc.