Published November 5, 2012 | Version v1
Journal article

Paradoxes of the Standard Adiabatic Born-Oppenheimer Approach to Collision Processes. Their Origin and Possible Solutions

Creators

  • 1. Department of Theoretical Physics, Herzen University, St. Petersburg 191186 (Russian Federation)

Description

It is demonstrated that conventional applications of the standard adiabatic Born-Oppenheimer approach lead to paradoxes such as nonzero inelastic cross sections for noninteracting collision systems and infinite inelastic collision cross sections. The origin of these paradoxes is the molecular state problem. The quantum solution of the problem, the multielectron reprojection method, is proposed within the standard BO approach.

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/388/9/092005

Additional details

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
388
Journal Issue
9
Journal Page Range
[1 p.]
ISSN
1742-6596

Conference

Title
27. international conference on photonic, electronic and atomic collisions
Acronym
ICPEAC 2011
Dates
27 Jul - 2 Aug 2011
Place
Belfast, Northern Ireland (United Kingdom)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
44033601
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ADIABATIC APPROXIMATION; ATOM COLLISIONS; BORN-OPPENHEIMER APPROXIMATION; CROSS SECTIONS; INELASTIC SCATTERING; MATHEMATICAL SOLUTIONS; MOLECULE COLLISIONS
Descriptors DEC
APPROXIMATIONS; CALCULATION METHODS; COLLISIONS; SCATTERING