Published May 2009 | Version v1
Journal article Metadata-only

Synthesis and X-ray structural analysis of hydrido(thiolato) platinum(II) complexes

Creators

  • 1. Saitama Univ., Graduate School of Science and Engineering, Saitama (Japan)

Description

The oxidative addition of [Pt(η2-nb)(PPh3)2] with a sterically hindered thiol, TripSH (4, Trip=9-triptycyl) in toluene afford cis-hydrido(thiolato) PtII complex [PtH(STrip)(PPh3)2](5), as thermally and moisture-stable colorless crystals in 91% yield. Complex 5 was fully characterized by 1H, 13C{1H}, and 31P{1H} NMR and IR spectroscopies, and the molecular structure of 5 was determined by X-ray crystallography. (author)

Availability note (English)

Available from http://dx.doi.org/10.1246/cl.2009.400

Additional details

Identifiers

DOI
10.1246/cl.2009.400;

Publishing Information

Journal Title
Chemistry Letters (Tokyo)
Journal Volume
38
Journal Issue
5
Journal Page Range
p. 400-401
ISSN
0366-7022

INIS

Country of Publication
Japan
Country of Input or Organization
Japan
INIS RN
40088381
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CARBON 13; CHEMICAL SHIFT; CRYSTAL STRUCTURE; HYDROGEN 1; INFRARED SPECTRA; J-J COUPLING; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; PHOSPHORUS 31; PLATINUM 195; PLATINUM COMPLEXES; PLATINUM HYDRIDES; SAMPLE PREPARATION; THIOLS; X-RAY DIFFRACTION
Descriptors DEC
CARBON ISOTOPES; COHERENT SCATTERING; COMPLEXES; COUPLING; DAYS LIVING RADIOISOTOPES; DIFFRACTION; DIMENSIONS; EVEN-ODD NUCLEI; HEAVY NUCLEI; HYDRIDES; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INTERMEDIATE COUPLING; INTERNAL CONVERSION RADIOISOTOPES; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; LENGTH; LIGHT NUCLEI; MAGNETIC RESONANCE; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHOSPHORUS ISOTOPES; PLATINUM COMPOUNDS; PLATINUM ISOTOPES; RADIOISOTOPES; RESONANCE; SCATTERING; SPECTRA; STABLE ISOTOPES; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
14 refs., 2 figs., 3 schemes