Published December 1989 | Version v1
Journal article

Crystalline molybdovanadium compounds of [Se2Mo2V6O28]6-, [MoV9O28]5-, [VMo5O19]3-anions

  • 1. Kishinevskij Gosudarstvennyj Univ., Kishinev (USSR)

Description

Crystalline compounds of three types: (NH3-CH2-CH2-NH3)2Na2[Se2Mo2V6O28] · 8H2O (1), [(CH3)4N]2Na2NH4[MoV9O28] · 5H2O (2), [(CH3)4N]2NH4[VMo5O19] (3) are isolated in Se4+-Mo6+-V5+-HCl system. For the first type of crystals on the basis of results of chemical analysis a formula of mixed decavanadate including simultaneously selenium(4), molybdenum(6) and vanadium(5) is suggested. Crystals (2), (3) are identified on the basis of chemical analysis, IR and 51V NMR spectra

Additional details

Additional titles

Original title (Russian)
Кристаллические молибдованадиевые соединения анионов [Се

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
34
Journal Issue
12
Series
Zh. Neorg. Khim.
Journal Page Range
3094-3097
ISSN
0044-457X
CODEN
ZNOKA