Published January 20, 1989
| Version v1
Journal article
Intramolecular cycloalkylation of phenylalkanols in the presence of sulfuric acid
- 1. A.A. Zhdanov Irkutsk State Univ. (USSR)
Description
The distribution of the deuterium in the benzocyclenes formed during the intermolecular cycloalkylation of 2-R-4-pheynl-2-butanol (R=CD3, CD2CH3, CH2CD3) in the presence of 85% sulfuric acid was investigated by NMR spectroscopy and mass spectrometry. Hydrogen exchange takes place at the stage of formation of the γ-phenylalkyl cation, the average lifetime of which is sufficient for the establishment of an isotopic equilibrium by successive elimination and addition of a deuteron
Additional details
Publishing Information
- Journal Title
- Journal of Organic Chemistry of the USSR (English Translation)
- Journal Volume
- 24
- Journal Issue
- 8
- Series
- J. Org. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 1525-1529
- ISSN
- 0022-3271
- CODEN
- JOCYA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 21034866
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- ALKYLATION; BUTANOLS; CATALYSIS; CATIONS; CYCLOALKANES; DEUTERATION; DEUTERIUM; DEUTERIUM COMPOUNDS; DEUTERONS; EQUILIBRIUM; HYDROGEN TRANSFER; HYDROGEN 1; ISOTOPE EFFECTS; ISOTOPE RATIO; ISOTOPIC EXCHANGE; MASS SPECTRA; MOLECULAR STRUCTURE; NMR SPECTRA; RADIOMETRIC ANALYSIS; SULFURIC ACID
- Descriptors DEC
- ALCOHOLS; ALKANES; CHARGED PARTICLES; CHEMICAL ANALYSIS; CHEMICAL REACTIONS; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; HYDROXY COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IONS; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; SPECTRA; STABLE ISOTOPES; SULFUR COMPOUNDS
Optional Information
- Notes
- Transl.: Cover-to-cover translation of Zhurnal Organicheskoj Khimii (USSR).