Synthesis and Characterization of Schiff Base Metal Complexes and Reactivity Studies with Maleimide Epoxy Resin
- 1. Bangalore University, Karnataka (India)
- 2. Technion-Israel Institute of Technology, Haifa (Israel)
- 3. Karnatak University, Karnataka (India)
- 4. National Institute of Technology-Karnataka, Surathkal (India)
Description
A novel malemide epoxy containing Co(II), Ni(II) and Cu(II) ions have been synthesized by curing malemide epoxy resin (MIEB-13) and Co(II), Ni(II) and Cu(II) complexes of macrocyclic bis-hydrazone Schiff base. The Schiff base was synthesized by reacting 1,4-dicarbnyl phenyl dihydrazide with 2,6-diformyl-4-methyl phenol. The Schiff base and its Co(II), Ni(II) and Cu(II) complexes have been characterized by elemental analyses, spectral (IR, 1H NMR, UV-vis., FAB mass, ESR), thermal and magnetic data. The curing reaction of maleimide epoxy compound with metal complexes was studied as curing agents. The stability of cured samples was studied by thermo-gravimetric analyses and which have excellent chemical (acid/alkali/solvent) and water absorption resistance. Further, the scanning electron microscopy (SEM) and definitional scanning colorimetric (DSC) techniques were confirmed the phase homogeneity of the cured systems
Additional details
Publishing Information
- Journal Title
- Bulletin of the Korean Chemical Society
- Journal Volume
- 33
- Journal Issue
- 2
- Series
- 37 refs, 15 figs, 6 tabs
- Journal Page Range
- p. 473-482
- ISSN
- 0253-2964
INIS
- Country of Publication
- Korea, Republic of
- Country of Input or Organization
- Korea, Republic of
- INIS RN
- 45088495
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION; COPPER IONS; REACTIVITY; RESINS; SCANNING ELECTRON MICROSCOPY; SCHIFF BASES; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS
- Descriptors DEC
- CHARGED PARTICLES; CHEMICAL ANALYSIS; ELECTRON MICROSCOPY; GRAVIMETRIC ANALYSIS; IMINES; IONS; MICROSCOPY; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC POLYMERS; PETROCHEMICALS; PETROLEUM PRODUCTS; POLYMERS; QUANTITATIVE CHEMICAL ANALYSIS; SORPTION; THERMAL ANALYSIS