Published 1975
| Version v1
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Oxidation of variable valence cations by ozone
Description
This paper deals with some aspects concerning the behavior of ozone in nitric acid solutions. The distribution of ozone between aqueous solutions and gaseous phase and the kinetics of ozone degradation in these solutions are studied. The mechanisms of this degradation are discussed. Ozone interaction with ions of Np(4), Pu(4) and some other metals is considered. Stoichiometric coefficients, rate constants and thermodynamic factors of the activation of these reactions are determined. The probable mechanisms of these reactions have been proposed
Availability note (English)
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8289411.pdf
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Additional details
Additional titles
- Subtitle (English)
- Communication 1
- Original title (Russian)
- Окисление катионов переменной валентности озоном
- Original subtitle (Russian)
- Soobshchenie 1.
Publishing Information
- Imprint Pagination
- 27 p.
- Report number
- RI--48
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 8289411
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; NEPTUNIUM COMPOUNDS; NITRIC ACID; OZONE; PLUTONIUM COMPOUNDS; THERMODYNAMIC PROPERTIES
- Descriptors DEC
- ACTINIDE COMPOUNDS; DISPERSIONS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; KINETICS; MIXTURES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; SOLUTIONS; TRANSURANIUM COMPOUNDS
Optional Information
- Notes
- 53 refs.; 9 tables; 2 figs.