Published August 18, 1986
| Version v1
Journal article
One- and two-dimensional 90.5-MHz 13C-NMR spectroscopy of the N-linked triantennary oligosaccharide units of calf fetuin
Creators
- 1. Tel Aviv Univ. (Israel). School of Chemistry
- 2. Weizmann Inst. of Science, Rehovoth (Israel). Dept. of Organic Chemistry
Description
Complete assignments of all anomeric resonances in the proton and carbon spectra of the N-linked oligosaccharide units of fetuin were made using one- and two-dimensional NMR spectroscopy. The authors are able to confirm the presence of microheterogeneity in the N-acetylneuraminic acid linkages to the galactose residues and the presence of a unique triantennary structure which carries a side chain: NeuAcα(1-3)Galβ(1-3)GlcNacβ(1-4)-. Anomeric carbon chemical shifts changes resulting from long-range conformational effects were observed. (Auth.)
Additional details
Publishing Information
- Journal Title
- FEBS (Fed. Eur. Biochem. Soc.) Lett.
- Journal Volume
- 204
- Journal Issue
- 2
- Series
- FEBS (Fed. Eur. Biochem. Soc.) Lett.
- Journal Page Range
- 257-260
- ISSN
- 0014-5793
- CODEN
- FEBLA
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- Netherlands
- INIS RN
- 18031645
- Subject category
- S60: APPLIED LIFE SCIENCES;
- Descriptors DEI
- CARBON 13; CHEMICAL SHIFT; COWS; FETUSES; GLYCOPROTEINS; MOLECULAR STRUCTURE; NMR SPECTRA; NUCLEAR MAGNETIC RESONANCE; OLIGOSACCHARIDES
- Descriptors DEC
- ANIMALS; CARBOHYDRATES; CARBON ISOTOPES; CATTLE; DOMESTIC ANIMALS; EVEN-ODD NUCLEI; ISOTOPES; LIGHT NUCLEI; MAGNETIC RESONANCE; MAMMALS; NUCLEI; ORGANIC COMPOUNDS; PROTEINS; RESONANCE; RUMINANTS; SACCHARIDES; SPECTRA; STABLE ISOTOPES; VERTEBRATES
Optional Information
- Notes
- 15 refs.; 2 figs.; 1 table.