Published December 2017
| Version v1
Journal article
Synthesis and Crystal Structure of a Four-coordinated Cobalt Complex with 1-Methylbenzimidazole
Creators
- 1. Yuncheng University, Department of Applied Chemistry (China)
- 2. Xichang Satellite Launch Center, Department of Technology and Service (China)
Description
A four-coordinated complex, L2Co(NCO)2, (L = 1-methylbenzimidazole) has been synthesized and characterized by IR spectroscopy, elemental analyses, and single crystal X-ray diffraction. The crystal is monoclinic, a = 14.522(2) Å, b = 14.610(2) Å, c = 8.6850(13) Å, β = 92.037(3)°, Z = 4, sp. gr. P21/c. Bond lengths Co–N(L) are equal to 2.0165(16) and 2.0174(15) Å, Co–O(NCO) are 1.944(2) and 1.945(2) Å. Intermolecular C–H···O, C–H···N, and C–H···π interactions link the molecules into three-dimensional networks in the crystal.
Additional details
Identifiers
Publishing Information
- Journal Title
- Crystallography Reports
- Journal Volume
- 62
- Journal Issue
- 7
- Journal Page Range
- p. 1109-1112
- ISSN
- 1063-7745
- CODEN
- CYSTE3
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 50001161
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BOND LENGTHS; COBALT COMPLEXES; INFRARED SPECTRA; INTERACTIONS; MOLECULES; MONOCLINIC LATTICES; MONOCRYSTALS; SYNTHESIS; X-RAY DIFFRACTION
- Descriptors DEC
- COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIFFRACTION; DIMENSIONS; LENGTH; SCATTERING; SPECTRA; THREE-DIMENSIONAL LATTICES; TRANSITION ELEMENT COMPLEXES
Optional Information
- Copyright
- Copyright (c) 2017 Pleiades Publishing, Inc.