Published June 21, 2000
| Version v1
Journal article
Spatial structure of transition metal complexes in solution determined by EXAFS spectroscopy
Description
CdK EXAFS, ZnK and CuK EXAFS and XANES spectra were measured for solutions of cadmium, zinc and copper dialkyldithiocarbamates in organic solvents with varying donating abilities: tributylphosphine, methylene chloride, benzene, dibutylsulfide, pyridine, dimethylsulfoxide and for some model compounds. The parameters of the local surroundings of the Cd, Zn and Cu atoms for complex forms in solutions were determined using EXAFS spectroscopy. Spatial structure models of the complex forms in a metal chelate - nonaqueous solvent system are suggested
Additional details
Identifiers
- PII
- S0168900299007123;
Publishing Information
- Journal Title
- Nuclear Instruments and Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and Associated Equipment
- Journal Volume
- 448
- Journal Issue
- 1-2
- Journal Page Range
- p. 345-350
- ISSN
- 0168-9002
- CODEN
- NIMAER
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 34045181
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; BENZENE; CADMIUM; CARBAMATES; COPPER; DMSO; ORGANIC SOLVENTS; PYRIDINES; SOLUTIONS; TBPO; THIOUREAS; X-RAY SPECTROSCOPY; ZINC
- Descriptors DEC
- AROMATICS; AZINES; CARBONIC ACID DERIVATIVES; CARBOXYLIC ACID SALTS; DISPERSIONS; ELEMENTS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROCARBONS; METALS; MIXTURES; NONAQUEOUS SOLVENTS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHINE OXIDES; PHOSPHINES; PHOSPHORUS COMPOUNDS; SOLVENTS; SPECTROSCOPY; SULFOXIDES; TRANSITION ELEMENTS
Optional Information
- Copyright
- Copyright (c) 2000 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.