Published September 25, 2007
| Version v1
Journal article
Quantum separation of para- and ortho-fulvene with coherent light: The influence of the conical intersection
Creators
- 1. Institut fuer Chemie und Biochemie, Freie Universitaet Berlin, Takustr. 3, 14195 Berlin (Germany)
- 2. Department of Chemistry and Chemical Technology, Al-Quds University, P.O. Box 20002, Jerusalem, Palestinian Authority (Israel)
Description
We investigate the effect of non-radiative decay via a conical intersection on the intra-molecular torsion of para- and ortho-fulvene by means of quantum dynamical simulations. Moreover, we demonstrate that a previously proposed method for separation of nuclear spin isomers with wavepacket interferometry [O. Deeb et al., Chem. Phys. Chem. 8 (2007) 322] can be applied even if non-radiative decay competes against wavepacket interference
Availability note (English)
Available from http://dx.doi.org/10.1016/j.chemphys.2007.05.020Additional details
Identifiers
- DOI
- 10.1016/j.chemphys.2007.05.020;
- PII
- S0301-0104(07)00180-2;
Publishing Information
- Journal Title
- Chemical Physics
- Journal Volume
- 338
- Journal Issue
- 2-3
- Journal Page Range
- p. 252-258
- ISSN
- 0301-0104
- CODEN
- CMPHC2
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 39094595
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- COHERENT RADIATION; INTERFERENCE; INTERFEROMETRY; ISOMERS; QUANTUM MECHANICS; SIMULATION; SPIN; TORSION; VISIBLE RADIATION; WAVE PACKETS
- Descriptors DEC
- ANGULAR MOMENTUM; ELECTROMAGNETIC RADIATION; MECHANICS; PARTICLE PROPERTIES; RADIATIONS
Optional Information
- Copyright
- Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.