Published April 1983 | Version v1
Journal article Metadata-only

Radiation ionic polymerization at low temperatures. Cyclopentadiene in glassy matrix of butyl chloride

Creators

  • 1. AN SSSR, Moscow. Inst. Khimicheskoj Fiziki

Description

The kinetics of ionic polymerization of cyclopentadiene in the butyl chloride matrix has been studied by the method of low-temperature postirradiation polymerization at softening of glassy system. This process does not require any special methods of drying of the monomer and solvent. The depression of polymerization by opical bleaching or introducing of compound containing atoms with non-divided electronic pair proves the cationic mechanism of the reaction at low temperatures

Additional details

Additional titles

Original title (Russian)
Радиационная ионная полимеризация при низких температурах. Циклопентадиен в стеклообразной матрице хлористого бутила

Publishing Information

Journal Title
Vysokomol. Soedin., Ser. A
Journal Volume
25
Journal Issue
4
Series
Vysokomol. Soedin., Ser. A.
Journal Page Range
818-821
ISSN
0507-5475

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
15012634
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; COBALT 60; CYCLOPENTADIENE; GLASS; IONS; LOW TEMPERATURE; ORGANIC CHLORINE COMPOUNDS; POLYMERIZATION; RADIATION DOSES
Descriptors DEC
ALKENES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHARGED PARTICLES; CHEMICAL REACTIONS; COBALT ISOTOPES; CYCLOALKENES; DIENES; HYDROCARBONS; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTO; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; KINETICS; MINUTES LIVING RADIOISOTOPES; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; POLYENES; RADIATION EFFECTS; RADIOISOTOPES; REACTION KINETICS; YEARS LIVING RADIOISOTOPES

Optional Information

Notes
For English translation see the journal Polymer Science USSR (USA).