FeS2 assisted degradation of atrazine by bentonite-supported nZVI coupling with hydrogen peroxide process in water: Performance and mechanism

Highlights: • ATZ degradation by B-nZVI/H₂O₂ process was enhanced in the presence of FeS₂. • High Fe²⁺ was favorable to H₂O₂ decomposition by B-nZVI/FeS₂/H₂O₂ process. • OH was dominant radical, and contributed to 86.1% of the overall ATZ removal. • Possible pathways of ATZ degradation were proposed based on intermediate products. • Enhanced mechanism for ATZ degradation by B-nZVI/FeS₂/H₂O₂ process was proposed. In this study, bentonite-supported nZVI (B-nZVI) was used as a catalyst to activate H₂O₂ for atrazine (ATZ) degradation in the presence of FeS₂. Results indicated that ATZ degradation by B-nZVI/H₂O₂ process was significantly enhanced when FeS₂ was introduced, and nearly 98% of ATZ was degraded by B-nZVI/FeS₂/H₂O₂ process within 60 min under the optimum conditions. ATZ degradation of B-nZVI/FeS₂/H₂O₂ process was much higher than the sum of B-nZVI and FeS₂/H₂O₂ processes. The presence of HCO₃⁻, PO₄³⁻ and F⁻ exhibited significant negative effects on the ATZ degradation, whereas both Cu²⁺ and Ni²⁺ exhibited positive effects on that. Both citric acid (CA) and ethylenediaminetetraacetic acid (EDTA) with lower concentration enhanced ATZ degradation rate, but significant suppression effects on that with higher concentration. The degradation of ATZ and 2,4-Dichlorophenol (2,4-DCP) could be simultaneously achieved in B-nZVI/FeS₂/H₂O₂ process under certain conditions. High soluble Fe²⁺ induced an excellent decomposition of H₂O₂ by B-nZVI and FeS₂. OH was dominant radical, and contributed to nearly 86% of the overall ATZ removal. A total of five intermediate products of ATZ were identified, and ATZ degradation was achieved via de-alkylation and hydroxylation processes. An enhanced reaction mechanism for ATZ degradation by B-nZVI/FeS₂/H₂O₂ process was proposed, and B-nZVI/FeS₂/H₂O₂ process exhibited an excellect catalytic performance within four successive runs.