Published October 2003 | Version v1
Journal article

Nonrelativistic variationally optimized exchange potentials for Ne-like atomic ions having large atomic number

  • 1. Department of Physics, University of Antwerp, Groenenborgerlaan 171, Antwerp (Belgium)
  • 2. Oxford University, Oxford (United Kingdom)
  • 3. Department of Applied Mathematics, University of Western Ontario, London, Ontario (Canada)

Description

In an earlier study, the exchange energy density εx(r) has been calculated analytically for Ne-like atomic ions in the nonrelativistic limit of large atomic number Z. Here, though now by numerical methods based on the optimized exchange potential approximation, corresponding results are obtained for Vx(r) for such ten-electron ions at large Z. The approach to the bare Coulomb limiting form of the 1/Z expansion is considered in some detail, as are corrections to the Slater potential VxSl(r), given in terms of the exchange energy density and ground-state density ρ(r) by 2εx(r)/ρ(r)

Additional details

Identifiers

Publishing Information

Journal Title
Physical Review. A
Journal Volume
68
Journal Issue
4
Journal Page Range
p. 044502-044502.4
ISSN
1050-2947
CODEN
PLRAAN

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
36082372
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ATOMIC IONS; ATOMIC NUMBER; CORRECTIONS; DENSITY FUNCTIONAL METHOD; ELECTRONS; ENERGY DENSITY; GROUND STATES; MULTICHARGED IONS; OPTIMIZATION; POTENTIAL ENERGY; POTENTIALS
Descriptors DEC
CALCULATION METHODS; CHARGED PARTICLES; ELEMENTARY PARTICLES; ENERGY; ENERGY LEVELS; FERMIONS; IONS; LEPTONS; VARIATIONAL METHODS

Optional Information

Notes
(c) 2003 The American Physical Society