Published 1992
| Version v1
Book
Synthesis, structure and reactivity of mixed-ring uranium(III) complexes
Description
(C5R5)UI2(THF)3 (R = Me, H) reacts with K2C8H7R (R = TMS, H) to yield the mixed-ring complexes (C5R5) (C8H7R)U(THF). These species will coordinate other neutral Lewis bases, such as 4,4'-dimethyl-2,2'-dipyridyl and Ph3PO. The spectroscopic and structural characterization of these compounds is described. Products obtained from oxidation reactions of (C5Me5) (C8H8)U(THF) are also discussed, such as [(C5Me5) (C8H8)UI]x, which can be prepared by reaction of (C5Me5) (C8H8)U(THF) with trimethylsilyliodide or I2. This complex crystallizes as an infinite chain with uranium centers bridged by iodide anions
Additional details
Publishing Information
- Publisher
- American Chemical Society.
- Imprint Place
- Washington, DC (United States)
- Imprint Title
- 203rd American Chemical Society national meeting
- Imprint Pagination
- 2442 p.
- Journal Page Range
- p. 1052, Paper INOR 148.
Conference
- Title
- 203. American Chemical Society (ACS) national meeting.
- Dates
- 5-10 Apr 1992.
- Place
- San Francisco, CA (United States).
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 26000144
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CHEMICAL PREPARATION; CHEMICAL REACTIONS; CYCLOALKENES; MOLECULAR STRUCTURE; URANIUM COMPLEXES; URANIUM IODIDES
- Descriptors DEC
- ACTINIDE COMPLEXES; ACTINIDE COMPOUNDS; ALKENES; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; IODIDES; IODINE COMPOUNDS; ORGANIC COMPOUNDS; SYNTHESIS; URANIUM COMPOUNDS
Optional Information
- Secondary number(s)
- CONF-920444--.