Published November 2009 | Version v1
Journal article

Line intensities of acetylene: New measurements in the 1.5-μm spectral region and global modelling in the ΔP=10 series

  • 1. Laboratory of Theoretical Spectroscopy, Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, 1, Akademicheskii av., 634055 Tomsk (Russian Federation)
  • 2. UPMC Univ Paris 06, UMR 7092, Laboratoire de Physique Moleculaire pour l'Atmosphere et l'Astrophysique, Case courrier 76, 4, place Jussieu, 75252 Paris Cedex 05 (France)
  • 3. CNRS, UMR 7092, Laboratoire de Physique Moleculaire pour l'Atmosphere et l'Astrophysique, Case courrier 76, 4, place Jussieu, 75252 Paris Cedex 05 (France)
  • 4. Groupe de Spectrometrie Moleculaire et Atmospherique, CNRS, UMR 6089, Universite de Reims-Champagne-Ardenne, Faculte des Sciences, BP 1039, 51687 Reims Cedex 2 (France)

Description

Using the Fourier transform spectra of the acetylene molecule recorded near 1.5-μm, the intensities of 111 lines belonging to seven hot bands of the main isotopologue 12C2H2 have been retrieved by means of a multispectrum fitting procedure. Considering the density of lines in the spectra, and the fact that the measured bands are the weakest observed, the accuracy of the measurements is around 10%. At first stage, an empirical treatment of these data has been performed, leading to the vibrational transition dipole moment squared and some Herman-Wallis coefficients. Then the measured line intensities of this work and collected ones from the literature have been treated simultaneously within the framework of the effective operator approach.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jqsrt.2009.04.012

Additional details

Identifiers

DOI
10.1016/j.jqsrt.2009.04.012;
PII
S0022-4073(09)00164-2;

Publishing Information

Journal Title
Journal of Quantitative Spectroscopy and Radiative Transfer
Journal Volume
110
Journal Issue
17
Journal Page Range
p. 1815-1824
ISSN
0022-4073
CODEN
JQSRAE

Optional Information

Copyright
Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.