Published November 2009
| Version v1
Journal article
Line intensities of acetylene: New measurements in the 1.5-μm spectral region and global modelling in the ΔP=10 series
Creators
- 1. Laboratory of Theoretical Spectroscopy, Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, 1, Akademicheskii av., 634055 Tomsk (Russian Federation)
- 2. UPMC Univ Paris 06, UMR 7092, Laboratoire de Physique Moleculaire pour l'Atmosphere et l'Astrophysique, Case courrier 76, 4, place Jussieu, 75252 Paris Cedex 05 (France)
- 3. CNRS, UMR 7092, Laboratoire de Physique Moleculaire pour l'Atmosphere et l'Astrophysique, Case courrier 76, 4, place Jussieu, 75252 Paris Cedex 05 (France)
- 4. Groupe de Spectrometrie Moleculaire et Atmospherique, CNRS, UMR 6089, Universite de Reims-Champagne-Ardenne, Faculte des Sciences, BP 1039, 51687 Reims Cedex 2 (France)
Description
Using the Fourier transform spectra of the acetylene molecule recorded near 1.5-μm, the intensities of 111 lines belonging to seven hot bands of the main isotopologue 12C2H2 have been retrieved by means of a multispectrum fitting procedure. Considering the density of lines in the spectra, and the fact that the measured bands are the weakest observed, the accuracy of the measurements is around 10%. At first stage, an empirical treatment of these data has been performed, leading to the vibrational transition dipole moment squared and some Herman-Wallis coefficients. Then the measured line intensities of this work and collected ones from the literature have been treated simultaneously within the framework of the effective operator approach.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jqsrt.2009.04.012Additional details
Identifiers
- DOI
- 10.1016/j.jqsrt.2009.04.012;
- PII
- S0022-4073(09)00164-2;
Publishing Information
- Journal Title
- Journal of Quantitative Spectroscopy and Radiative Transfer
- Journal Volume
- 110
- Journal Issue
- 17
- Journal Page Range
- p. 1815-1824
- ISSN
- 0022-4073
- CODEN
- JQSRAE
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 44000983
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; ACCURACY; ACETYLENE; CARBON 12; DENSITY; DIPOLE MOMENTS; FOURIER TRANSFORM SPECTROMETERS; INFRARED SPECTRA; MOLECULES; SIMULATION
- Descriptors DEC
- ALKYNES; CARBON ISOTOPES; EVEN-EVEN NUCLEI; HYDROCARBONS; ISOTOPES; LIGHT NUCLEI; MEASURING INSTRUMENTS; NUCLEI; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SPECTROMETERS; SPECTROSCOPY; STABLE ISOTOPES
Optional Information
- Copyright
- Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.