Published March 20, 1986 | Version v1
Journal article Metadata-only

Hydrophosphorylation of alkynes with phosphinous acids

Creators

  • 1. V. I. Lenin Moscow State Pedagogic Institute, USSR

Description

A feature of the homolytic hydrophosphorylation of alkynes, as compared with alkenes, is more ready addition of phosphinous acids in presence of benzoyl peroxides. A difference was found in the hydrophosphorylation of acetylenes with dibutylphosphinous acid and with diarylphosphinous acids: the latter tend to form diaddition products

Additional details

Publishing Information

Journal Title
J. Gen. Chem. USSR (Engl. Transl.)
Journal Volume
55
Journal Issue
10
Series
J. Gen. Chem. USSR (Engl. Transl.).
Journal Page Range
2010-2015
ISSN
0022-1279
CODEN
JGCHA

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
19039641
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Translation
Descriptors DEI
ADDUCTS; ALKYNES; BENZOYL PEROXIDE; CARBON 13; CHEMICAL REACTION YIELD; CHEMICAL SHIFT; CHLOROFORM; COUPLING CONSTANTS; DEUTERIUM COMPOUNDS; HYDROGEN 1; ISOMERS; J-J COUPLING; NMR SPECTRA; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHORUS 31; PHOSPHORYLATION; SYNTHESIS
Descriptors DEC
CARBON ISOTOPES; CHEMICAL REACTIONS; COUPLING; EVEN-ODD NUCLEI; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INTERMEDIATE COUPLING; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXYGEN COMPOUNDS; PEROXIDES; PHOSPHORUS ISOTOPES; SPECTRA; STABLE ISOTOPES

Optional Information

Notes
Translated from Zh. Obshch. Khim.; 55: No. 10, 2263-2269(Oct 1985).