Published October 2007 | Version v1
Journal article Metadata-only

TTA solvation kinetics in the ionic liquid BumimTf2N

Creators

  • 1. IPHC/DRS, Chimie Nucleaire, 67 - Strasbourg (France)
  • 2. Institut de Physique Nucleaire, 91 - Orsay (France)
  • 3. CEA Saclay, Dir. de l'Energie Nucleaire (DEN/DANS/DPC), Service de chimie physique, 91 - Gif sur Yvette (France)

Description

TTA, a classical complexing agent of metallic cations, has been studied by UV-vis in the ionic liquid (IL) 1-methyl-3-butyl-imidazolium bis-triflimide (BumimTf2N), in the presence of variable amounts of water. Depending on the water content, the keto-hydrate/enol equilibrium kinetics can last up to tens of hours. Modelling by use of classical homogeneous kinetic equations appears unsatisfactory, which pledges for the existence of non-homogeneous phenomena in such solutions, most probably related to the state of water in ILs. (authors)

Availability note (English)

Available from doi: <http://dx.doi.org/10.1016/j.crci.2007.04.007

Additional details

Identifiers

DOI
10.1016/j.crci.2007.04.007;

Publishing Information

Journal Title
Comptes Rendus. Chimie
Journal Issue
no.10-11t.10
Journal Page Range
p. 1117-1121
ISSN
1631-0748

INIS

Country of Publication
France
Country of Input or Organization
France
INIS RN
39020436
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL REACTION KINETICS; SOLVATION; TTA
Descriptors DEC
HETEROCYCLIC COMPOUNDS; KETONES; KINETICS; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; REACTION KINETICS

Optional Information

Notes
22 refs.