Published January 25, 2010 | Version v1
Journal article

What is atomic structures of (ZnO)34 magic cluster?

  • 1. Department of Physics, Huaiyin Normal University, Jiangsu 223001 (China)
  • 2. Department of Physics, Yancheng Institute of Technology, Jiangsu 224051 (China)
  • 3. Laboratory of Materials Modification by Laser, Electron, and Ion Beams, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)
  • 4. Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Jiangsu, 223001 (China)

Description

Recent experiment on the mass spectrum of ZnO clusters revealed a (ZnO)34 magic cluster with enhanced stability [A. Dmytruk, et al., Microelect. J. 40 (2009) 218]. We have performed an extensive search for the most stable structure of (ZnO)34 using gradient-corrected density-functional theory. Instead of the previously nominated onion-like nested cage of (ZnO)6-(ZnO)28, we found that the hollow cage structures satisfying the isolated six square rule constitute the most preferred structural motif for (ZnO)34 cluster.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.physleta.2009.11.085

Additional details

Identifiers

DOI
10.1016/j.physleta.2009.11.085;
PII
S0375-9601(09)01519-9;

Publishing Information

Journal Title
Physics Letters. A
Journal Volume
374
Journal Issue
6
Journal Page Range
p. 850-853
ISSN
0375-9601
CODEN
PYLAAG

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
41112901
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ATOMIC CLUSTERS; DENSITY FUNCTIONAL METHOD; MASS SPECTRA; STABILITY; ZINC OXIDES
Descriptors DEC
CALCULATION METHODS; CHALCOGENIDES; OXIDES; OXYGEN COMPOUNDS; SPECTRA; VARIATIONAL METHODS; ZINC COMPOUNDS

Optional Information

Copyright
Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.