Published February 2023
| Version v1
Journal article
Formation of MPd3+x (M = Gd, Np) by the reaction of MN with Pd and chlorination of MPd3+x using cadmium chloride
- 1. Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki-ken (Japan). Nuclear Science and Engineering Center
Description
The formation of MPd3+x (M = Gd, Np) by the reaction of MN with Pd at 1323 K in Ar gas flow was observed. Cubic AuCu3-type GdPd3.3 (a = 0.4081 ± 0.0001 nm) and NpPd3 (a = 0.4081 ± 0.0001 nm) were identified, respectively. The product obtained from the reaction of NpN with Pd contained additional phases, including the hexagonal TiNi3-type NpPd3. Chlorination of the MPd3+x (M = Gd, Np) samples was accomplished by the solid-state reaction using cadmium chloride at 673 K in a dynamic vacuum. (author)
Additional details
Publishing Information
- Journal Title
- Journal of Radioanalytical and Nuclear Chemistry
- Journal Volume
- 332
- Journal Issue
- 2
- Journal Page Range
- p. 503-510
- ISSN
- 0236-5731
- CODEN
- JRNCDM
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 54028597
- Subject category
- S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
- Descriptors DEI
- ACTINIDES; CHLORINATION; MIXED NITRIDE FUELS; PLATINUM; PYROCHEMICAL REPROCESSING; TRANSMUTATION
- Descriptors DEC
- CHEMICAL REACTIONS; ELEMENTS; ENERGY SOURCES; FUELS; HALOGENATION; MATERIALS; METALS; NUCLEAR FUELS; PLATINUM METALS; REACTOR MATERIALS; REPROCESSING; SEPARATION PROCESSES; SOLID FUELS; TRANSITION ELEMENTS
Optional Information
- Notes
- 59 refs.