Published November 28, 1990
| Version v1
Journal article
15N NMR spectroscopic investigation of nitrous and nitric acids in sulfuric acid solutions of varying acidities
Creators
- 1. Univ. of Southern California, Los Angeles (USA)
Description
Both nitrous and nitric acids were studied in sulfuric acid solutions of varying acid strengths by 15N NMR spectroscopy. The study gives new insights into the nature of intermediates present at different acid strengths. Furthermore, we have also discovered a novel redox reaction between NO2+ and NO+ ions involving the intermediacy of their respective acids. A mechanism is proposed to explain the observed results. 13 refs., 2 figs., 1 tab
Additional details
Publishing Information
- Journal Title
- Inorganic Chemistry
- Journal Volume
- 29
- Journal Issue
- 24
- Series
- Inorg. Chem.
- Journal Page Range
- 4965-4968
- ISSN
- 0020-1669
- CODEN
- INOCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 22049689
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CHEMICAL REACTIONS; EXPERIMENTAL DATA; NITRIC ACID; NITROGEN 15; NITROUS ACID; NMR SPECTRA; SULFURIC ACID
- Descriptors DEC
- DATA; HYDROGEN COMPOUNDS; INFORMATION; INORGANIC ACIDS; INORGANIC COMPOUNDS; ISOTOPES; LIGHT NUCLEI; NITROGEN COMPOUNDS; NITROGEN ISOTOPES; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; OXYGEN COMPOUNDS; SPECTRA; STABLE ISOTOPES; SULFUR COMPOUNDS